Enzymatic polymerization of plant-derived phenols for material-independent and multifunctional coating

Enzymatic Polymerization of Phenols in Room Temperature Ionic Liquids.

Soybean peroxidase (SBP) was used to catalyze the polymerization of phenols in room-temperature ionic liquids (RTILs). Phenolic polymers with number average molecular weights ranging from 1200 to 4100 D were obtained depending on the composition of the reaction medium and the nature of the phenol. Specifically, SBP was highly active in methylimidazolium-containing RTILs, including 1-butyl-3-met...

Bubble Elimination for Coating Material

Bubbles in coating color greatly influence the paper quality and coater runnability. It is particularly important technology to remove bubbles for the paper coating industry. Recently, one of the authors has developed a novel device using swirl flow capable of eliminating bubbles and decreasing dissolved gases from fluid. This device is called the “Bubble Eliminator”. Using the bubble eliminato...

Enzymatic determination of phenols using peanut peroxidase.

The influence of phenol and its derivatives on the kinetics of oxidation of aryldiamines (indicator-substrates) catalyzed by novel plant peroxidase-cationic peanut peroxidase-was studied. The character of influence of phenols on the kinetics of enzymatic oxidation of benzidine, o-dianisidine, and 3,3',5,5'-tetramethylbenzidine (TMB) with hydrogen peroxide was found to depend on a correlation be...

Regioselective Enzymatic Carboxylation of Bioactive (Poly)phenols

In order to extend the applicability of the regioselective enzymatic carboxylation of phenols, the substrate scope of o-benzoic acid (de)carboxylases has been investigated towards complex molecules with an emphasis on flavouring agents and polyphenols possessing antioxidant properties. o-Hydroxycarboxylic acid products were obtained with perfect regioselectivity, in moderate to excellent yields...

Use of Plant Material for the Removal of Pollutants by Polymerization and Binding to Humic Substances